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In most cases, on a freshly non-partitioned drive, you can just choose the default as show in the screenshot below. Next, select your drive and select the system and boot partition. Then it will need to format your drive, there you can select the default which is MBR partition scheme and click OK. Then select the version of the OS you want to use. Then launch WinToUSB and the first thing it will do is ask you to find your ISO (or DVD) version of Windows.
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There is NO weird toolbar or other crapware that the installer tries to sneak on your computer. Start by installing WinToUSB and follow the installation wizard and accepting the default settings.
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